Group E gets underway on Monday afternoon with two sides who will both fancy their chances of a knockout-round appearance as Romania take on Ukraine in Munich.
Romania surprised the continent by topping Group I with an unbeaten record in qualifying, ahead of tournament regulars Switzerland, while Ukraine overcame two tricky play-off encounters with Bosnia-Herzegovina and Iceland to reach the finals in Germany.
Romania v Ukraine is available to watch live in the UK and will be broadcast on BBC One and BBC iPlayer.
Romania v Ukraine will be played at the Allianz Arena in Munich with kick-off due for 14:00 BST on Monday 17th June.
Romania just edge the head-to-head record with three wins from their six meetings, but each of those came in their first three encounters between 2001 and 2003.
Ukraine came out on top in their most recent fixture back in 2016 in what was a friendly for the ages, as former West Ham star Andriy Yarmolenko and Arsenal full-back Oleksandr Zinchenko got on the scoresheet in a 4-3 victory.
Romania wins | 3 |
Draws | 1 |
Ukraine wins | 2 |
* H2H stats refer to all competitions
Edward Iordanescu has a fully fit squad to select from, however goalless draws against Bulgaria and Liechtenstein in their warm-up matches means their attacking line-up could be difficult to nail down, with George Puscas, Denis Alibec and Denis Dragus all pushing for a starting berth.
Serhiy Rebrov will be without left-back Vitaliy Mykolenko for their group opener after the Everton man sustained an ankle injury, meaning Oleksandr Zinchenko will be expected to fill the void. Girona striker Artem Dovbyk finished as top goalscorer in La Liga last season and should lead the line for the Blue & Yellow.