Plymouth Argyle host Southern League Premier Division Central outfit Worcester City in the first round of the FA Cup on Saturday afternoon.
The Pilgrims currently occupy a play-off place in League One following a solid start to the season under the stewardship of Tom Cleverley.
Alvechurch operate in the seventh tier in English football and they have overcome four qualifying rounds to reach the first round proper of this season's FA Cup.
Highlights of FA Cup first round matches including Plymouth v Alvechurch will be available to stream via BBC iPlayer and the BBC Sport website.
A live broadcast of the match is not currently available in the UK.
Plymouth v Alvechurch will be played at Home Park in Plymouth and kick-off is at 15:00 GMT on Saturday 7th November.
Odds will display when the market is available.
Min deposit requirement. Free Bets are paid as Bet Credits and are available for use upon settlement of qualifying bets. Min odds, bet and payment method exclusions apply. Returns exclude Bet Credits stake. Time limits and T&Cs apply.