Four matches are scheduled in La Liga on Saturday, with reigning champions Barcelona back in action at home against Celta Vigo.
Xavi's side breezed past Royal Antwerp in midweek in the Champions League and they will feel confident of chalking up another victory against Celta.
Elsewhere, high-flying Girona host Mallorca, Osasuna take on Sevilla and rock-bottom Almeria play Valencia, who have made an impressive start to the campaign.
Picking out bets from all four matches, our four-fold pays out at more than 11/1.
Girona v Mallorca - Under 2.5 goals @ 8/13
Osasuna v Sevilla - Double chance Sevilla @ 1/2
Barcelona v Celta Vigo - Barcelona to win to nil @ 6/5
Almeria v Valencia - Valencia win @ 11/8
Acca pays more than 11/1
Odds were correct at the time of writing and subject to change.
View the latest Football odds here
Girona v Mallorca - Under 2.5 goals @ 8/13
Girona will look to extend their unbeaten start to the season when they play host to Mallorca on Saturday afternoon.
Michel's side drew 1-1 at Real Sociedad on the opening weekend before racing up four straight victories over Getafe, Sevilla, Las Palmas and Granada.
As for Mallorca, they had to wait until last week for their first win and they have amassed five points from their opening five fixtures.
Aside from a 3-2 defeat to Granada, Mallorca's matches have been low-scoring affairs and under 2.5 goals has landed in their four other games.
While Girona have been more free-flowing in the final third, under 2.5 goals has also landed in two of their five assignments and it would be no surprise to see this bet come in on Saturday.
Osasuna v Sevilla - Double chance Sevilla @ 1/2
Osasuna might be three points better off than Sevilla, but the table does not tell the whole story ahead of Saturday's clash.
Los Nervionenses have played one game less in the league than their opponents, and the recent signs suggest there is more to come from Jose Luis Mendilibar's group.
Sevilla are unbeaten in two, including a 1-1 draw against Lens in the Champions League, and they are expected to start pushing up the table.
Osasuna have lost back-to-back games to Barcelona and Getafe heading into this fixture, conceding five goals in the process, but both of those defeats have come by a one-goal margin so it shows they are competing well.
It may prove prudent in this one to back Sevilla in the Double Chance market, as this offer more cover than going for them in the Full Time Result option.
Barcelona v Celta Vigo - Barcelona to win to nil @ 6/5
Champions Barcelona have maintained their form from last season under Xavi, winning six games in succession in all competitions.
The Spanish giants have racked up the goals since they returned from the international break, too, scoring 10 goals in total, five against Real Betis in the league and the same in the Champions League victory over Antwerp.
Celta Vigo have endured a slow start to the campaign, winning just once, and they have failed to trouble the scoresheet in three of their first five league matches.
Barca lost when the two teams last met in June, but they should cruise to victory this time around with a clean sheet.
Almeria v Valencia - Valencia win @ 11/8
After a difficult few years, Valencia have finally given their fans something to smile about at the start of the new season.
Los Che have won three of their first five games in La Liga to move into the top five, and they should have no problems overcoming Almeria.
Almeria have picked up one point from five matches and shipped 11 goals, a combination which leaves them rooted to the bottom of the table.
Girona v Mallorca - Under 2.5 goals @ 8/13
Osasuna v Sevilla - Double chance Sevilla @ 1/2
Barcelona v Celta Vigo - Barcelona to win to nil @ 6/5
Almeria v Valencia - Valencia win @ 11/8
Acca pays more than 11/1
Odds were correct at the time of writing and subject to change.
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